ASTM D6579-11(2024) PDF

ASTM D6579-11(2024) PDF

1.1This practice covers the determination of apparent molecular weight (MW) averages and molecular weight distributions (MWD) for THF-soluble hydrocarbon, rosin and terpene resins by size-exclusion chromatography (SEC). This technique is not absolute; it requires calibration with standards of known molecular weight. This practice is applicable to resins containing molecular-weight components that have elution volumes falling within the elution volume range defined by polystyrene standards.

Note 1:SEC is also known as gel permeation chromatography (GPC).

1.2SEC systems employ low-volume liquid chromatography components and columns packed with relatively small (generally 3 μm to 20 μm) microporous particles. High-performance liquid chromatography instrumentation and automated data handling systems for data acquisition and processing are also required.

1.3The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.